The Heegner Numbers. These are the n such that ℚ[√-n] has unique factorisation. There are exactly 9 of them:
1, 2, 3, 7, 11, 19, 43, 67, 163.
A famous fact about them is that 163 being a Heegner Number leads to e^(π√163) being very close to a whole number.
262537412640768743.99999999999925…