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Nitrogen Asphyxiation in the workplace is insanely dangerous specifically because humans (and most animals) don't have a way to detect nitrogen displacement...
The body detects hypoxia by build up of CO2, or more accurately carbonic acid, not loss of O2 - it doesn't expect for nitrogen to be the thing to displace all the oxygen, so you literally don't notice it. There's countless stories of people fainting and dying due to not realising the situation they were in.
So how in fuck's name did Alabama manage to botch it so badly that the first guy had an agonising death via seizure?? It takes a special kind of neglect to make that happen.
I think it just didn't end up working as well as scientists thought it would. Maybe there's more to painless nitrogen execution besides just filling a container with nitrogen. It's not like they can just test a nitrogen death chamber before rolling it out. We'll see if the next execution goes the same way or not.
I think the problem was that they didn't actually use a chamber and instead tried to use a mask, IIRC